(5Z)-5-(2-Hydroxybenzylidene)-3-phenyl-2-thioxo-1,3-thiazolidin-4-one
نویسندگان
چکیده
In the title compound, C(16)H(11)NO(2)S(2), the dihedral angles between the heterocyclic ring and the phenyl and anilinic benzene rings are 9.68 (13) and 79.26 (6)°, respectively, and an intra-molecular C-H⋯S inter-action occurs. In the crystal, inversion dimers linked by pairs of O-H⋯O hydrogen bonds occur, leading to R(2) (2)(10) loops, and C-H⋯O and weak C-H⋯π inter-actions further consolidate the packing.
منابع مشابه
(5Z)-5-(2-Hydroxybenzylidene)-2-thioxo-1,3-thiazolidin-4-one methanol hemisolvate
In the title compound, C(10)H(7)NO(2)S(2)·0.5CH(3)OH, the dihedral angle between the aromatic rings is 11.43 (11)° and a short intra-molecular C-H⋯S contact occurs. The methanol solvent mol-ecule is equally disordered over two sets of sites. In the crystal, inversion dimers linked by pairs of N-H⋯O hydrogen bonds occur. The methanol solvent mol-ecule connects the dimers through O-H⋯S and O-H⋯O ...
متن کامل(5Z)-5-(2-Methylbenzylidene)-3-phenyl-2-thioxo-1,3-thiazolidin-4-one
In the title compound, C(17)H(13)NOS(2), the heterocyclic ring is oriented at a dihedral angle of 74.43 (5)° with respect to the anilinic benzene ring and at a dihedral angle of 17.31 (9)° with respect to phenyl ring. An intra-molecular C-H⋯S inter-action occurs, resulting in an S(6) ring. In the crystal, the packing is consolidated by C-H⋯π inter-actions and possible very weak aromatic π-π sta...
متن کامل3-Phenyl-2-thioxo-1,3-thiazolidin-4-one
In the mol-ecule of the title compound, C(9)H(7)NOS(2), the heterocycle and the phenyl ring are oriented at a dihedral angle of 72.3 (1)°. Adjacent mol-ecules are connected through C-H⋯O inter-actions.
متن کامل3-(3-Methylphenyl)-2-thioxo-1,3-thiazolidin-4-one
In the title compound, C(10)H(9)NOS(2), the dihedral angle between the rhodanine (2-thioxo-1,3-thia-zolidin-4-one) and 3-methyl-phenyl rings is 83.30 (3)°. The H atoms of the methyl group are disordered over two set of sites with an occupancy ratio of 0.58 (3):0.42 (3). In the crystal, the mol-ecules inter-act by way of C-H⋯π and C=O⋯π inter-actions.
متن کامل3-(2-Methylphenyl)-2-thioxo-1,3-thiazolidin-4-one
In the title compound, C(10)H(9)NOS(2), the 1,3-thia-zolidine and 2-methyl-phenyl rings are oriented at a dihedral angle of 84.44 (9)°. In the crystal, an unusual bifurcated C-H⋯(O,π) inter-action leads to zigzag chains of mol-ecules.
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